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酯氨解反應催化劑 – LiTFSI(LiNTf2)雙三氟甲烷磺酰亞胺鋰

This post is part of the series LiTFSI - 應用

Other posts in this series:

  1. 酯氨解反應催化劑 – LiTFSI(LiNTf2)雙三氟甲烷磺酰亞胺鋰 (Current)
  2. 環氧開環反應催化劑 – LiNTf2(LiTFSI)雙三氟甲烷磺酰亞胺鋰



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LiNTf2-Catalyzed Aminolysis of Lactones with Stoichiometric Quantities of Amines

Abstract: LiNTf2 in the reaction of lactones with amines is able to
activate cyclic esters towards ring opening, thus leading to clean
open-chain amides under mild conditions and using a stoichiometric
amount of amine. The generality of the method was demonstrated
by a range of selected lactones and amines.
Key words: amides, ring opening, Lewis acids, lactones, catalysis


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